Reese Witherspoon and Ryan Phillippe in Cruel Intentions
Reese Witherspoon and Ryan Phillippe would actually go on to get married later in life. They had an obvious chemistry on-set. This classic '90s movie had its fair share of steamy moments.
Ryan Gosling and Michelle Williams in Blue Valentine
Even though Gosling and Williams' characters have their ups and downs, their on-screen chemistry is palpable. The film follows them and their horrifically toxic relationship that leads to the end of their marriage. Their intimate scenes are some of the driving forces behind the plot.
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